Municipal solid waste processing facility and commercial ethanol production process
Filing Information
- Patent Number: US6267309
- Application Number: US9354665
- Filing date: 07/16/1999
- Issue date: 07/31/2001
- Predicted expiration date: 12/23/2013
- U.S. Classifications: 241/17 · 241/241.1 · 241/23 · 241/241.2 · 241/21 ·
- International Classifications: --
- International Classifications: 241 17 · 241 20 · 241 21 · 241 23 · 241 2411 · 241 2412 · 241 27 ·
- Related U.S. Application Data:
CROSS REFERENCE TO RELATED APPLICATIONS
This application is a continuation of U.S. application Ser. No. 09/076,890, filed May 13, 1998, now U.S. Pat. No. 5,975,439, which is a continuation of U.S. application Ser. No. 08/717,909, filed Sep. 23, 1996, issued as U.S. Pat. No. 5,779,164, Jul. 14, 1998, which is a continuation of U.S. application Ser. No. 08/422,585, filed Apr. 14, 1995, issued as U.S. Pat. No. 5,571,703, Nov. 5, 1996, which is a continuation-in-part of U.S. application Ser. No. 08/351,017, filed Dec. 7, 1994, abandoned, which is a continuation-in-part of U.S. application Ser. No. 08/291,045 filed Aug. 12, 1994, issued as U.S. Pat. No. 5,407,817, Apr. 18, 1995, which is a continuation-in-part of U.S. application Ser. No. 08/172,202, filed Dec. 23, 1993, abandoned, the contents of each of which are fully incorporated by reference herein.
Abstract
A method of processing waste is disclosed wherein the municipal solid waste is segregated and processed to recover reusable rubber, metal, plastic, glass and the remaining organic portion of the waste stream is used to make ethanol and other chemicals. One process utilizes a pretreatment step with dilute sulfuric acid to reduce the heavy metal content of the cellulosic component of the municipal solid waste which can inhibit the fermentation of the sugars obtained from such waste. In another, the heavy metal content of the cellulosic component of municipal solid waste is removed via an ionic exchange process, after hydrolysis with sulfuric acid. A process for an economical, energy efficient production of ethanol from municipal solid waste is also disclosed.References Cited
U.S. Patent Documents
Foreign Patent Documents
| Document Number | Assignees | Inventors | Issue/Pub Date |
|---|---|---|---|
| DE2919518 | UTIKAL HANS DR | Nov 1980 | |
| EP0005703 | John Lester Lang | Dec 1979 | |
| GB1116888 | BOEHRINGER & SOEHNE GMBH | Jun 1968 | |
| PL171260 | PRZED PROD HANDLOWO USLUGOWE E | Aug 1993 |
Other Publications
| “Ethanol From Cellulosic Residues and Crops: Annual Report,” Tennessee Valley Authority (Oct. 1987). |
| “Integrated Fuel Alcohol Production Systems, Phase III: Experimental Facility Testing Report for the period of Jan. 15, 1984 - Jan. 15, 1985,” Tennessee Valley Authority, Office of Agricultural and Chemical Development. |
| Rossiter, G., “ISEP, A Moving Bed Contractor for Chromatographic Separations: Advanced Separation Technologies Incorporated,” presented at the 4th Workshop on Preparative HPLC, Salzburg, Austria, Mar. 28-31, 1993. |
| Supplemental European Search Report for EP 95 90 5989, (Mailed Jul. 19, 2000). |
| English language translation of EP 0 005 703, Document No. AP1. |
| English language translation of DE 29 19 518, Document No. AL2. |
| English language translation of PL 171260, Document No. AM2. |
Referenced By
| Document Number | Assignee | Inventors | Issue/Pub Date |
|---|---|---|---|
| US6987183 | Danisco Sweeteners Oy | Heikki Heikkila et al. | Jan 2006 |
| US6419828 | Controlled Environmental Systems Corporation | Lawrence J. Russo, Jr. | Jul 2002 |
| US7135308 | Propulsion Logic, LLC | Ronnie A. Bush et al. | Nov 2006 |
| US7497392 | Alliance Technology Group, Inc. | Olaf Nathan Lee et al. | Mar 2009 |
Patent Family
The current document is not in a family.Independent Claims | See all claims (12)
- 1. A method for producing ethanol from the cellulosic component of municipal solid waste, comprising the following steps: (a) shredding the cellulosic component of municipal solid waste; (b) treating the cellulosic component obtained in step (a) with about 1:1 concentrated sulfuric acid to solid component, by weight, at about 30° to 80° C. to give a partially hydrolyzed mixture; (c) diluting the partially hydrolyzed mixture obtained in step (b) with water at a temperature of about 80° to 100° C. to give a diluted mixture containing about 2 to 6 parts water to about 1 part partially hydrolyzed mixture, by weight; (d) agitating the diluted mixture obtained in step (c) to give a digested mixture; (e) removing the solids from the digested mixture obtained in step (d) to give a filtrate; (f) separating the filtrate obtained in step (e) into an acid containing solution and a sugar containing solution; (g) concentrating the sugar containing solution obtained in step (f) to about 12-14% sugar; (h) adjusting the pH of the concentrated sugar containing solution obtained in step (g) to about 6; (i) fermenting with yeast the solution obtained in step (h) to give a beer; (j) removing the yeast from the beer obtained in step (i) to give a filtered beer; and (k) recovering the ethanol from the filtered beer obtained in step (j).
- 8. A method for producing ethanol from the cellulosic component of municipal solid waste, comprising the following steps: (a) shredding the cellulosic component of municipal solid waste; (b) treating the cellulosic component obtained in step (a) with about 1:1 concentrated sulfuric acid to solid component, by weight, at about 30° to 80° C. to give a partially hydrolyzed mixture; (c) diluting the partially hydrolyzed mixture obtained in step (b) with water at a temperature of about 80° to 100° C. to give a diluted mixture containing about 2 to 6 parts water to about 1 part partially hydrolyzed mixture by weight; (d) agitating the diluted mixture obtained in step (c) to give a digested material; (e) removing the solids from the digested mixture obtained in step (d) to give a filtrate; (f) separating the filtrate obtained in step (e) into an acid containing solution and a sugar containing solution; (g) concentrating the sugar containing solution obtained in step (f) to about 12-14% sugar; (h) adjusting the pH of the concentrated sugar containing solution obtained in step (g) to about 6; (i) fermenting with yeast the solution obtained in step (h) to give a beer; (j) removing the yeast from the beer obtained in step (i) to give a filtered beer; (k) distilling the ethanol from the filtered beer obtained in step (j); (l) drying the insoluble component obtained in step (e); and (m) burning the dry insoluble component obtained in step (l) as a fuel to provide heat for the distillation of ethanol in step (k) from the filtered beer obtained in step (j).





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