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US6984265: Three dimensional array films
Filing Information
Patent Family
38 Claims, 9 Drawings
Abstract
The present invention provides nanoparticle film and methods of making such films. The nanoparticle film comprises a three dimensional cross-linked array of nanoparticles and linker molecules. The nanoparticle film is coherent, robust and self supporting. The film may be produced by adding linker molecules to a suspension of nanoparticles. The linker molecules form cross-links between the nanoparticles. Prior to completion of the cross-linking reaction the cross-linked nanoparticles are separated from the suspension.
- 1. A method of forming a coherent nanoparticle film, the method comprising the following steps:
(i) adding to a suspension of nanoparticles linker molecules which form cross-links between the nanoparticles to start a cross-linking reaction; and
(ii) separating the cross-linked nanoparticles from the suspension prior to completion of the cross-linking reaction to obtain a coherent nanoparticle film.
- 5. A method of forming a multilayer film comprising at least two layers of coherent nanoparticle film, the method comprising the following steps:
(i) adding to a suspension of nanoparticles linker molecules which form cross-links between the nanoparticles to start a cross-linking reaction;
(ii) passing the suspension from step (i) through a porous support prior to completion of the cross-linking reaction to form a nanoparticle film on the porous support;
(iii) adding to a further suspension comprising nanoparticles linker molecules which form cross-links between the nanoparticles to start a cross-linking reaction;
(iv) passing the further suspension from step (iii) through the nanoparticle film of step (ii) and the porous support prior to completion of the cross-linking reaction to form a further nanoparticle film; and
(v) optionally repeating steps (iii) and (iv).
- 24. A nanoparticle film comprising a three dimensional cross-linked array of nanoparticles and linker molecules in which the nanoparticle film is coherent, robust and self supporting.
References Cited
U.S. Patent Documents
Foreign Patent Documents
* cited by examiner
Other Publications
| International Search Report for PCT/AU00/01210, dated Nov. 23, 2000. |
| International Preliminary Examination Report for PCT/AU00/01210. dated Aug. 21, 2001. |
| M. Musick et al., “Stepwise Construction of Conductive Au Colloid Multilayers from Solution”; Chem Mater. 1997, 9, pp. 1499-1501. |
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